News and Highlights
August 31, 2024: Article about Cobalt and Nickel Phosphides for CatalysisOur latest work from the ERC NanoFLP research program is out. Here we developped a large-scale robust synthesis of Co2P and Ni2P nanoparticles based on the commercial phosphine HETAP. We also showed that addition of a well-selected second phosphine was able to trigger a low-temperature catalytic hydrogenation of phenylacetylene. Read the article. With: Anthony, Sophie |
Another article out: Hydride formation on defective CeO2 monitored by NAP-XPSAs a follow-up on our work about reduced ceria nanoparticles, we used near-ambient-pressure XPS to characterize the surface state under H2 moderate pressure. We show that homolytic cleavege on Ce(III) sites is the main activation path at 100 °C, forming a significant amount of surface hydrides. This is a key insight to further develop ceria as a self-standing catalyst for low-temperature hydrogenation reactions. Read the article. With: Rémi, Sophie |
New article: Unveiling the effect of phosphines on Nickel NanocatalystsStill chasing NanoFLPs! as part as our ERC project, Karim and Anthony showed that well-chosen phosphines allow reducing the onset temperature of terminal alkyne hydrogenation in colloidal suspension of Ni nanoparticles. Read the article. With: Karim, Anthony, Sophie |
February 29, 2024: Congrats to Anthony!Anthony Ropp defended his PhD thesis with brio. Titled "Phosphine-enhanced activity of transition metal nanocatalysts for H2 activation", his work dealt with a variety of metal and metal phosphide nanoparticles decorated with phosphine ligands. Congrats! |
November 25, 2023: Agora des NanosI participated at Théâtre de la Ville to an exciting scientific mediation event: after a presentation of my activities to a group of students from Ecole Estiennes, they conceived and produced a poster for a broad public. Splendid work from their side! It allowed for a rich discussion with the public. A few other scientists were also invited to share their work wih the students, which made up for a very interesting poster session, for us, for them, and most importantly for a public keen to discuss about nanosciences. |
New article: Phosphines and Cobalt Phosphide Nano-UrchinsIn the quest of NanoFLPs, as part as our ERC project, Anthony and Rémi developped these fancy nano-urchins that are able to hydrogenate phenylacetylene when put in the presence of a well-chosen phosphine. Read the article. With: Anthony, Rémi, Sophie |
September 28, 2023: PhD Defense of Léna MeynielToday, Léna defended her PhD thesis, titled "Investigation of the Nano-Bio Interface by the Design and Development of Nanostructured Lanthanide Oxysulfide Thin Films using Ellipsometric and Electrochemical Techniques". Her work was co-supervised with Natacha Krins, from the RMES team of the lab. Congrats Léna! |
September, 2024: Now teaching on a regular basis!I joined in September the teaching staff of the Chemistry Department at Ecole Polytechnique. This appointment comes as a complementary position to my CNRS main position at Sorbonne University. I am honored and happy to contribute to showing the wonders of chemistry in my old school! |
Article out: Cerium(IV) as you never saw itWhile the literature contains tens of protocols to prepare cerium oxide nanoparticles from Ce(III) precursors, there is still an open question regarding the time at which the cerium oxidation occurs and the role of hydroxide phases in this process. This article identifies an oxyhydroxide phase of Ce(IV) of the chemical formula CeO(OH)2 as a key intermediate and proposes a crystal structure for it. Read the article. With: Rémi, Sophie |
Post-doc position openingThere is an opening to join the group as a post-doctoral fellow, from September 2023, on the "Modeling Surface Reactions on Ligand-Covered Metallic Nanoparticles". The project is in the scope of ERC NanoFLP and will be done in co-supervision with Dr. David Loffreda (ENS de Lyon). The candidate should have a a good knowledge of DFT applied to materials science and chemistry or catalysis. He/she may have already worked on the theoretical modeling of metallic nanoparticles at various scales or methodologies. %%% The position is now filled. %%% |
New article: Influence of the Cobalt Active Site Neighbors in NiCo Nanocatalysts for Phosphine-Assisted Silane ActivationNiCo nanoparticles are active catalysts at room temperature for Si−H bond activation. We designed nanoparticles with a nickel core and a limited amount of cobalt surface sites to clarify which of the two metals was the active site and if the neighbouring atoms influenced the reaction efficiency. The trend in catalytic activity is consistent with cobalt being the active site, and it shows a higher activity when its immediate neighbours are cobalt atoms. Read the article. With: Anthony, Sophie |
Post-doc position openingThere is an opening to join the group as a post-doctoral fellow, from May 2023, on the "Metal-Containing Nanoparticles for the Catalytic Activation of Small Molecules". The project is in the scope of ERC NanoFLP. The candidate should have a background in catalysis, homogeneous or heterogeneous, using nanoparticles or organometallic complexes. He/she should have a background in inorganic chemistry and materials science. %%% The position is now filled. %%% |
New article: Phosphine-Catalyzed Activation of Phenylsilane for Benzaldehyde ReductionHere, we studied the organocatalyzed hydrosilylation of benzaldehyde with a phosphine, introduced at 10 mol %, and phenylsilane at room temperature. The best results of the screening over 13 phosphines and phosphites were obtained with linear trialkylphoshines (PMe3, PnBu3, POct3), indicating the importance of their nucleophilicity. The products of the hydrosilylation were identified, allowing a monitoring of the concentration in the different species. Read the article. With: Rémi, Alberto, Cyprien, Sophie |
February 10, 2023: Journée annuelle de la chimieThis local workshop gathers colleagues from the Chemistry department of Sorbonne Université. I took this opportunity to share our recent results in an uncommon fashion: by telling the fairy tale of "Martine the phosphine"... an experiment in scientific mediation well received by the colleagues! |
January 13, 2023: Cyprien PhD DefenseCyprien defended his PhD thesis about "Borane adsorption on MgO nanoparticles for increased catalytic activity in the cycloaddition of CO2 on epoxides". Congrats to the new doctor! |
Article out! Thin film of Lanthanide Oxysulfide NanoplatesWe recently managed to form thin films of lanthanide oxysulfide nanoparticles using colloidal suspensions. The films are of optical quality and the bandgap of the nanoparticles is preserved. The thickness can be finely tuned using various concentration or multiple layer deposition. Read the article. With: Léna, Cédric, Natacha, Sophie |
October 21, 2022: Hybrid Materials International ConferenceI was invited to give an overiew of the group recent works during this international conference held in Genoa, Italy. Excellent opportunity to discuss the descriptor approach in nanochemistry! Check the program. |
July 25-29, 2022: Sol-gel International ConferenceThis conference was held in Lyon and gathered a broad community around sol-gel but also materials design, thin films and coatings etc. Léna presented her work on lanthanide oxysulfide thin film design while I was invited to give a broad overview of our recent works. Check the program. With: Léna, Sophie |
June 21-22, 2022: Workshop Carmen EvolutionI was invited to contribute to this prospective workshop organized by CARMEN, a joint laboratory about materials characterization and the energy transition. A fascinating variety of talks from contributors in several topics! Science and strategy were discussed together by academic and industrial players: check the program. |
Another accepted paper: Ni3C nanocatalysts for colloidal hydrogenationIn this work, we investigated the potential of well-defined hcp nickel carbide nanoparticles as hydrogenation catalyst for a range of chemical moities. We also looked at the effects of solvent polarity and the presence of water on the conversion. The full story here. With: Rémi, Léna, Sophie |
Paper accepted: Phase-controlled NiCo nanoparticlesWe all know that nanoparticles synthesis is a tricky job, especially when dealing with bimetallic air-sensitive compositions. Here, we investigated in details the role of many parameters for the preparation of core-shell NiCo nanoparticles presenting the sole fcc phase. Read the paper. With: Alberto, Cyprien, Alexy, Anthony, Sophie |
March 14-18, 2022: CatEnerChem SchoolThis week, I am attending this interdisciplinary school as a member of the organization comittee. We will learn about five key molecules for the catalysis and energy challenges, hearing from chemists and also colleagues from social sciences. Anthony and Cyprien will present posters as participants. Follow us here. With: Cyprien, Anthony, Sophie |
Feb 11, 2022: Post-doc position openingThere is an opening to join the group as a post-doctoral fellow, from April 2022, on the "Colloidal catalysis under soft reaction conditions for the activation of small molecules". The project is in the scope of ERC NanoFLP. The candidate should have a strong background in catalysis, homogeneous or heterogeneous, using nanoparticles or organometallic complexes. He/she should have a background in inorganic chemistry and materials science. %%% The position is now filled %%% |
Jan 28, 2022: Article outWe just published our interdisciplinary work titled "Risk Analysis and Technology Assessment of Emerging (Gd,Ce)2O2S Multifunctional Nanoparticles: An Attempt for Early Safer-by-Design Approach". This is a highly collaborative study in the framework of the PhD thesis of Anh-Minh Nguyen. Check the paper! With: Minh, Olivier, Corinne, Sophie, and more! |
Dec 6, 2021: PhD Defense of Antoine PesesseAntoine defended today his PhD thesis, titled "Synthèse de nanoparticules contenant des métaux pour la catalyse assistée par des bases de Lewis en suspension colloïdale". The jury was enthousiastic about the discussion that followed. Congrats! |
Oct 7, 2021: PhD Defense of Rémi AndréRémi defended today his PhD thesis, titled "Tailored routes to metal-containing nanoparticles for hydrogenation reactions in solution: surface design for H2 activation", in front of an enthousiastic jury and audience. Congrats! |
Sept 29, 2021: European Conference on Green and Sustainable ChemistryRémi presented online his recent work on metal carbide nanoparticles at this international conference broadly interested in a more sustainable world. With: Rémi |
Sept 23, 2021: GECAT invited webinarIn relation with the Young Researcher Award from the Catalysis division of the French Chemical Society, I was invited to present our latest results at the "Jeudis du GECAT", a national webinar series that appeared in 2020 and is very successful amongst colleagues. This was a great exchange with the broad catalysis community, thanks all for your feedbacks. |
Article on Nickel-Cobalt NanoFLPVery happy to share our first publication proposing the concept of NanoFLP, that is, nanoparticles as partners in Frustrated Lewis Pairs. We investigated the activation of Si-H bonds by Lewis acid NiCo nanoparticles and a series of phosphines as Lewis base. We demonstrate the key effect of the Tolman cone angle on the success of the reaction, which strongly suggests that we achieved the formation of a NanoFLP in the colloidal solution. This is the key concept of ERC Starting Grant NanoFLP, a project that started in 2018. Read the paper. With: Alberto, Sophie |
Sept 13-15, 2021: Meeting on Nanosciences AdvancesThis week, I am participating to an onsite (!) conference about nanosciences. This is a highly interdisciplinary week under the auspices of the CNano network, in which I am presenting our recent paper on metal carbide nanoparticles. |
Article on Molybdenum L-edge XASCompared with Mo K-edge, the Mo L-edge is less often employed to analyze materials, catalysts or processes. In this article, we provide guidelines to measurement and a series of reference spectra, including some from air-sensitive compounds. This work was done with the team of B. Lassalle-Kaiser at synchrotron Soleil. Read the paper. With: Alexy, Rémi, Cyprien, Kim, Sophie |
July 9, 2021: Award from the French Chemical SocietyI am honored to be the recipient of the "Researcher Award" from the Solid State Chemistry Division of the French Chemical Society for year 2021. This yearly national award exists since 1977 and distinguished a number of chemists: here, the list of awardees. Many thanks to all the colleagues involved in our various projects since I joined CNRS in 2014! |
Accepted article on NanocarbidesIn this work, we discuss the solid-state metathesis reaction between metal chlorides and potassium dispersed in carbon, forming nano-carbides along other phases such as metals and hydrides.We decipher the phase speciation in relation with the experimental parameters to propose a unifying mechanism. Read the paper. With: Rémi, Florian, Alexy, Guillaume, Sophie |
July 5-8, 2021: Indisciplinary school on NanosciencesThis week, Léna participated to the annual summer school organized by the C'Nano network. She had the opportunity to learn about all branches of nanosciences and also to present a poster about her own work. With: Léna |
July 1-2, 2021: GecomMini (online)Another online conference this month. I was invited to give a keynote to this event organized each year around coordination chemistry (usually under the name "Gecom-Concoord"). I discussed in particular the reaction mechanisms leading to metal-containing nanoparticles, how we can design them and how we should monitor the nanoparticles for optimal development of their reactivity. |
June 29-30, 2021: Online conference of the Catalysis divisionIn relation with the online SCF21 conference, was held the symposium of the Catalysis division. Rémi and Antoine had the opportunity to discuss their respective works in the framework of ERC project NanoFLP and beyond. With: Rémi, Antoine |
June 24, 2021: Plenary conference for RJ-SCFIn relation with the online SCF21 conference, I was invited by the Young Chemist Network to give a plenary conference in their symposium. Great chance to share our latest results about nanoparticle design and reactivity and discuss with the younger generation. |
Accepted paper about Copper Nanoparticles SynthesisOur work dealing with the analysis of organic side-reaction during the synthesis of copper nanoparticles was just accepted. In this article, we also discuss the further catalytic activity of the copper nanoparticles formed in situ. Read the paper. With: Antoine, Sophie |
June 8, 2021: Nanosafety in l'Actualité ChimiqueThe young chemist netwwork of SCF just published an editorial about nanoparticles safety in l'Actualité Chimique. I was interviewed to try and shed some light on this tricky topic. Check the article. |
June 1st, 2021: DivCat Young Investigator AwardI was awarded this year the "Young Investigator award", shared with Thibault Cantat, from the Division of Catalysis of the French Chemical Society. I am honored to share the award with Thibault and thankful to the colleagues (older and younger) with whom I conduct research on a daily basis and through long-term collaborations. |
April 6-12, 2021: NAP-XPS at SoleilWe are now performing near-ambient-pressure x-ray photoelectron spectroscopy at TEMPO-B. This week, we look at a selection of nanoparticles stabilized by organic ligand for CO2 activation. Thanks to Jean-Jacques Gallet and Fabrice Bournel for hosting us on the beamline! With: Antoine, Anthony, Rémi, Alexy, Alberto, Cyprien and Sophie |
March 23-25, 2021: Operando spectroscopy on nanoparticlesThis week we are at ROCK beamline in SOLEILto run some colloidal catalysis and follow the structural changes of the nanocatalysts using hard x-ray absorption spectroscopy. A very nice interlude in the third covid-19 lockdown! With: Rémi, Alexy, Alberto, Anthony and Sophie |
Dec 11, 2020: European Innovation SummitI will participate to the event from Knowledge for Innovation (K4I) in a session titled "the role of early career professionnals in driving sustainable innovation". Our pannel will discuss several aspects, from leadership to entrepreneurship, and how blue-sky research is related to innovation. Follow us here on friday at 11 am. |
Dec 8, 2020: Nanoparticles & Conspiracy theoriesIn a long interview for the French radio France Inter, I answer to journalist Xavier de la Porte, who was curious as why nanoparticles are often mentionned in conspiracy theories. A nice opportunity to discuss the perception of nanoparticles, and more generally, of chemistry. Also, a chance to explain what we do in the labs and why I find this fascinating. Podcast in French. |
Dec 1, 2020: Joining the Early Career Advisory Board of ChemPlusChemSupporting Chemistry in Europe and promotting the involvment of early career chemists in policy making at all levels are two key actions I am happy to participate in. Joigning the Early Career Advisory Board of ChemPlusChem, a journal edited by ChemistryEurope, is a great way to do both. This is the second ECAB that I join, after these of ACS Catalysis. Great discussions ahead! |
Nov 9, 2020: Online Symposium of GDCh at University of RegensburgAt the invitation of German colleagues from GDCh, the German society of chemistry, I gave a talk during their online symposium organized on the topic of phosphorus chemistry. I presented our research program on metal phosphide nanoparticles. In a period void of regular meetings, this was a welcome opportunity to get feedback from the community on our most recent work. Thanks to the organizing committee. |
Oct 30, 2020: Second lockdown beginsSix months after the first lockdown, here we are again, with suppressed travel rights and strong limitations on our professional and personal lives. Hopefully, this time our students and post-docs are able to access the lab for a few days pe |
Oct 28, 2020: Bilateral Workshop with U. SydneyThis morning, I am presenting works from the Institute in a joint catalysis workshop from Sorbonne Université and University of Sydney. A nice opportunity to share our work with distant colleagues and learn about their expertise as well! |
Oct 7, 2020: Congrats to Dr. Kim LeToday, Kim defended her PhD, titled "Oxygen Reduction Reaction with Molybdenum-containing Oxysulfide Nanoparticles: from Colloidal Synthesis to Surface Activity" in front of a (half)-full room and with more public online. She is now a Doctor of Sorbonne Université: congrats! |
June 30-July 3, 2020: Back on SAMBAThis week we are studying XANES and EXAFS of air-sensitive colloidal solutions at SAMBA beamline. The picture shows our air-tight setup. Great to be back to SOLEIL after the lockdown period! Huge thanks to Andrea and Guillaume for making the experiment possible at short notice. With: Alexy, Alberto, Antoine, Sophie |
May 11, 2020: End of lockdown in FranceWhile the worst has past, universities and labs will take some time to reopen their doors. Meanwhile, we have now a well-established routine with one NanoSurf meeting per week and good practices for teleworking. |
April 28, 2020: Article in ChemNanoMatWe have been interested for a while by phase control in metal phosphide nanoparticles... now we achieved it for iron! A new P4-containing molecule for the synthesis, PDF for the structural investigation, and HER properties as a perspective. This project involved several colleagues from LCMCP, Collège de France and ETH Zürich. Read the paper. With: Florian, Rémi, Capucine, Sophie, and many others |
April 14, 2020: Interview for ChemCatChemFollowing the Clara Immerwahr Award, I was interviewed by the journal ChemCatChem (part of Chemistry Europe). Read here. |
March 31, 2020: Review on Metal Oxysulfides"Metal oxysulfides: from bulk compounds to nanomaterials": Everything you always wanted to know about these exquisite inorganic compounds, now published in an open-access journal. With: Clément, Sophie |
March 12, 2020: LCMCP SeminarAntoine presented his work at the lab in the weekly seminar series. He discussed copper-containing nanoparticles in the context of sustainable chemistry. With: Antoine |
March 4-7, 2020: At ROCK beamlineThis week, we are running experiments on the mechanism of formation of metal oxide and metal nanoparticles. We use the amazing Quick-EXAFS setup of ROCK beamline to measure XAS in solution during heating. Huge thanks to our colleagues on the beamline (especially: Valérie Briois and Laurent Barthe) for setting up the operando cell and helping us achieve the experiments! With: Alexy, Rémi, Antoine, Alberto, Cyprien, Sophie |
Feb. 28, 2020: Capturing Carbide ChemistryThanks to our colleague from the movie archives of CNRS, we captured a series of experiments on video, with professional quality. Now we will analyze these data and compare the reactions two by two! With: Rémi, Sophie |
Feb. 20, 2020: News from the Young ChemistsIn relation with the IUPAC2019 conference held in Paris, read about the Young Chemists Symposium and the General Assembly of IYCN in Chemistry International. You can also check our earlier article about the symposium in l'Actualité Chimique. |
Feb. 13-14, 2020: Visit to BerlinIn relation with the Clara Immerwahr award, I spent two days in Berlin, discussing with colleagues of TU Berlin, U. Potsdam and the Fritz Haber Institute about their work and how we could build new collaborations. I also had the opportunity to meet other women in chemistry (PhD students as well as colleagues)... nice continuation of the GWB2020 event the day before in Paris! |
Feb. 12, 2020: Global Women BreakfastThis year again, a Global Women Breakfast was organized at Sorbonne Université by Dr. Lydia Sosa-Vargas and colleagues, with the strong support of the Chemistry Department: a unique opportunity to network and discuss about Women in Chemistry! I also participated to a round table about leadership and the glass ceiling. |
Feb. 3, 2020: Video at SOLEILLet's embark in a tour of Soleil synchrotron and participate with us to a run on LUCIA! We were interviewed along with Benedikt Lassalle, the beamline scientist, about our experiments last July. Watch the video! (english subtitles available) With: Kim, Alexy, Rémi, Cyprien, Sophie |
Jan. 16-17, 2020: Soleil User MeetingI was invited to present the complementary input of a range of spectroscopies for the study of lanthanide oxysulfide nanoparticles at the 15th User Meeting of Soleil synchrotron. A great opportunity to keep in touch with this multidisciplinary community and learn more about advanced characterizations! |
Jan. 9, 2020 : Accepted Article on Gadolinium Oxysulfide NanoparticlesWe knew for years that sodium ions were mandatory to the formation of colloidal Gd2O2S nanoparticles... but we finally uncovered why! Read the story. With: Clément, Anh-Minh, Kim, Xavier and Sophie |
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